A Contact Angle Study of the Interaction between Embedded Amphiphilic Molecules and the PDMS Matrix in an Aqueous Environment
نویسندگان
چکیده
Poly(dimethylsiloxane) (PDMS) surface modification via gradient-induced transport of embedded amphiphilic molecules is a novel, easy, flexible, and environmentally friendly approach for reducing protein adsorption on PDMS in microfluidic applications. To better understand the processing and the potential use in the viability-sensitive applications such as manipulation and culturing of primary neural cells, we systematically investigate how embedded molecules interact with a PDMS matrix and its surface in aqueous environments by studying the wetting angle over time under various processing conditions, including water exposure time, water exposure temperature, curing master materials, in addition to comparing different embedded amphiphilic molecules. The results indicate that the water exposure time clearly plays an important role in the surface properties. Our interpretation is that molecular rearrangement of the surface-embedded molecules improves surface coverage in the short term; while over a longer period, the transport of molecules embedded in the bulk enhance its coverage. However, this improvement finally terminates when molecules transported from the bulk to the surface are not sufficient to replace the molecules leaching into the water. OPEN ACCESS Micromachines 2014, 5 516
منابع مشابه
Investigation of structural, morphological and dynamic mechanical properties of unvulcanized PDMS/silica compound
In this study, the interaction between the silica filler and polydimethylsiloxanes (PDMS) was investigated from the aspects of the bound rubber and morphological characterization. With special attention to the dynamic properties, the dynamic test was conducted by dynamic shear rheometer. The results show that the modified fillers disperse uniformly within PDMS matrix without aggregation and con...
متن کاملFabrication and characterization of polycarbonate/titanium oxide nanotubes mixed matrix membranes for efficient removal of cadmium and copper from aqueous solution
In this study, novel polycarbonate-titanium oxide nanotubes (PC-TNT) ultrafiltration mixed matrix membranes (MMMs) were fabricated for decontamination of Cd2+ and Cu2+ metal ions from aqueous solution. The weight percent of TNTs in the polycarbonate membrane matrix was changed from 0 to 15. The synthesized neat PC membrane and PC-TNTs MMMs were characterized with respect to structural morpholog...
متن کاملساخت و مشخصه یابی پوشش نانوکامپوزیتی PDMS-SiO2-CuO بر فولاد زنگ نزن و ارزیابی رفتار آبگریزی آن
Abstract: With the advances in the development of biomaterials for tissue replacement, the attention of scientists has been focused on the improvement of clinical implant properties. In this regard, despite the appropriate properties of the stainless steel, the application of stainless steel as implants has been limited due to the weak corrosion resistivity. The purpose of this paper was prepar...
متن کاملIn Vitro Cytotoxic Activity and Binding Properties of Curcumin in the Presence of β-Casein Micelle Nanoparticles
Curcumin (CUR) is the active curcuminoid with many physiological, biochemical, and pharmacological properties. Solubility and stability of CUR is the limiting factors for realizing its therapeutic potential. Bovine β-casein is an abundant milk protein that is highly amphiphilic and self-assembles into stable micellar nanoparticles in aqueous solution. β-Casein nanoparticle can solubilize CUR mo...
متن کاملSurface Modification of Silicone Rubber Membrane by Microwave Discharge to Improve Biocompatibility
Wetability of biocompatible polymers can be improved by plasma surface modification. The purpose of this study was to surface modify an experimental poly (dimethylsiloxane) rubber (PDMS) material in order to improve its wetability and biocompatibility. Surface properties of the PDMS were characterized using contact angles measurement for wetability analysis. Samples of experimental silico...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Micromachines
دوره 5 شماره
صفحات -
تاریخ انتشار 2014